Heat capacity of indium from 300 to 1000 K
Identifieur interne : 000910 ( Main/Exploration ); précédent : 000909; suivant : 000911Heat capacity of indium from 300 to 1000 K
Auteurs : RBID : ISTEX:10973_1978_Article_BF01912382.pdfAbstract
The heat capacity of high-purity indium has been determined by adiabatic-shield calorimetry in the range 300 to 1000 K. Values of thermodynamic functions have been calculated andCp (1000 K), [H° (1000 K)−H° (298.15 K)], and [S° (1000 K)−S° (298.15 K)] are (27.11±0.15) J K−1 mole−1, (22873±70) J mole−1, and (41.567 ±0.125) J K−1 mole−1, respectively. The enthalpy of fusion is (3283±7) J mole−1 and the melting temperature (429.77±0.01) K. The premelting heat capacity is compatible with the presence of a mole fractionx ≈ 1·10−6 of a liquid-soluble/solidinsoluble impurity in the sample.
DOI: 10.1007/BF01912382
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<record><TEI><teiHeader><fileDesc><titleStmt><title>Heat capacity of indium from 300 to 1000 K</title><author><name>F. Grønvold</name><affiliation wicri:level="1"><mods:affiliation>Department of Chemistry, University of Oslo, Blindern, Oslo 3, Norway</mods:affiliation><country xml:lang="fr">Norvège</country><wicri:regionArea>Department of Chemistry, University of Oslo, Blindern, Oslo 3</wicri:regionArea><wicri:noRegion>Oslo 3</wicri:noRegion></affiliation></author></titleStmt><publicationStmt><idno type="RBID">ISTEX:10973_1978_Article_BF01912382.pdf</idno><date when="1978">1978</date><idno type="doi">10.1007/BF01912382</idno><idno type="wicri:Area/Main/Corpus">000075</idno><idno type="wicri:Area/Main/Curation">000075</idno><idno type="wicri:Area/Main/Exploration">000910</idno></publicationStmt></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="eng">The heat capacity of high-purity indium has been determined by adiabatic-shield calorimetry in the range 300 to 1000 K. Values of thermodynamic functions have been calculated andCp (1000 K), [H° (1000 K)−H° (298.15 K)], and [S° (1000 K)−S° (298.15 K)] are (27.11±0.15) J K−1 mole−1, (22873±70) J mole−1, and (41.567 ±0.125) J K−1 mole−1, respectively. The enthalpy of fusion is (3283±7) J mole−1 and the melting temperature (429.77±0.01) K. The premelting heat capacity is compatible with the presence of a mole fractionx ≈ 1·10−6 of a liquid-soluble/solidinsoluble impurity in the sample.</div></front></TEI><mods xsi:schemaLocation="http://www.loc.gov/mods/v3 file:///applis/istex/home/loadistex/home/etc/xsd/mods.xsd" version="3.4" istexId="0d3d93ec52272aba9ef1b392c477256d0c33f20e"><titleInfo lang="eng"><title>Heat capacity of indium from 300 to 1000 K</title><subTitle>Enthalpy of fusion</subTitle></titleInfo><name type="personal"><namePart type="given">F.</namePart><namePart type="family">Grønvold</namePart><role><roleTerm type="text">author</roleTerm></role><affiliation>Department of Chemistry, University of Oslo, Blindern, Oslo 3, Norway</affiliation></name><typeOfResource>text</typeOfResource><genre>Original Paper</genre><originInfo><publisher>Kluwer Academic Publishers, Dordrecht</publisher><dateCreated encoding="w3cdtf">1977-09-02</dateCreated><dateValid encoding="w3cdtf">2005-06-24</dateValid><copyrightDate encoding="w3cdtf">1978</copyrightDate></originInfo><language><languageTerm type="code" authority="iso639-2b">eng</languageTerm></language><physicalDescription><internetMediaType>text/html</internetMediaType></physicalDescription><abstract lang="eng">The heat capacity of high-purity indium has been determined by adiabatic-shield calorimetry in the range 300 to 1000 K. Values of thermodynamic functions have been calculated andCp (1000 K), [H° (1000 K)−H° (298.15 K)], and [S° (1000 K)−S° (298.15 K)] are (27.11±0.15) J K−1 mole−1, (22873±70) J mole−1, and (41.567 ±0.125) J K−1 mole−1, respectively. The enthalpy of fusion is (3283±7) J mole−1 and the melting temperature (429.77±0.01) K. The premelting heat capacity is compatible with the presence of a mole fractionx ≈ 1·10−6 of a liquid-soluble/solidinsoluble impurity in the sample.</abstract><abstract lang="fre">La chaleur spécifique de l'indium de haute pureté a été déterminée entre 300 et 1000 K par calorimétrie adiabatique. Les valeurs des fonctions thermodynamiques suivantes ont été calculées:Cp (1000 K)=(27.11±0.15) J K−1mol−1, [H° (1000 K)−H° (298.15 K)]= (22 875±70) J mol−1 et [S° (1000 K)−S° (298.15 K)]=(41.567±0.125) J K−1 mol−1. L'enthalpie de fusion est (3283±7) J mol−1 et la température de fusion (429.77±0.01) K. La chaleur spécifique de pré-fusion est compatible avec la présence d'une fraction molairex≈1×10−6 d'une impureté dans l'échantillon, soluble dans le liquide, insoluble dans le solide.</abstract><abstract lang="ger">Die Wärmekapazität von hochreinem Indium wurde im Bereich von 300 bis 1000 K durch adiabatische Schildkalorimetrie bestimmt. Die Berechnungen der thermodynamischen Funktionen:Cp (1000 K), [H° (1000 K)−H° (298.15 K)] und [S° (1000 K−S° (298.15 K)] ergab 27.11±0.15 J K−1 Mol−1, (22 875±70) J Mol−1, bzw. (41.567±0.125) J K−1 Mol−1. Die Schmelzenthalpie beträgt (3283±7) J Mol−1 und die Schmelztemperatur (429.77±0.01) K. Die Vorschmelz-Wärmekapazität ist mit der Gegenwart einer Molfraktionx≈1×10−6 einer flüssig-löslich/fest-unlöslichen Verunreinigung in der Probe vereinbar.</abstract><abstract lang="und">C помощью адиабатичес ки-экранированной калориметрии была оп ределена теплоемкость высоко чистого индия в облас ти температур от 300 до 1000 К. Бы ли вычислены термодинамические ф ункции: Сp(1000 К), [Н∘ (1000 К) — H∘ (298,15 К)] и [S∘ (1000 К) — S∘ (298.15 К)], которые соот ветственно равны: 27.11±0.15 д ж. К−1. моль−1, 2 2875±70 дж. моль−1 и 41.567±0.125 дж. К− 1моль−1. Энтальпия плавления составлял а 3283±7 дж.моль−1, а температ ура плавления − 429.77±0,01 К. Теплоемкость предва рительного плавления совместим и с присутствием жидкостно-растворим ой/твердотельнонера створимой примеси в образце с мо льной фракцией х ≈ 1.10−6.</abstract><relatedItem type="series"><titleInfo type="abbreviated"><title>Journal of Thermal Analysis</title></titleInfo><titleInfo><title>Journal of thermal analysis</title><partNumber>Year: 1978</partNumber><partNumber>Volume: 13</partNumber><partNumber>Number: 3</partNumber></titleInfo><genre>Archive Journal</genre><originInfo><dateIssued encoding="w3cdtf">1978-06-01</dateIssued><copyrightDate encoding="w3cdtf">1978</copyrightDate></originInfo><subject usage="primary"><topic>Chemistry</topic><topic>Inorganic Chemistry</topic><topic>Physical Chemistry</topic><topic>Polymer Sciences</topic><topic>Measurement Science, Instrumentation</topic></subject><identifier type="issn">0022-5215</identifier><identifier type="issn">Electronic: 1572-8943</identifier><identifier type="matrixNumber">10973</identifier><identifier type="local">IssueArticleCount: 20</identifier><recordInfo><recordOrigin>Wiley Heyden Ltd., Chichester and Akadémiai Kiadó, Budapest, 1978</recordOrigin></recordInfo></relatedItem><identifier type="doi">10.1007/BF01912382</identifier><identifier type="matrixNumber">Art1</identifier><identifier type="local">BF01912382</identifier><accessCondition type="use and reproduction">MetadataGrant: OpenAccess</accessCondition><accessCondition type="use and reproduction">AbstractGrant: OpenAccess</accessCondition><accessCondition type="restriction on access">BodyPDFGrant: Restricted</accessCondition><accessCondition type="restriction on access">BodyHTMLGrant: Restricted</accessCondition><accessCondition type="restriction on access">BibliographyGrant: Restricted</accessCondition><accessCondition type="restriction on access">ESMGrant: Restricted</accessCondition><part><extent unit="pages"><start>419</start><end>428</end></extent></part><recordInfo><recordOrigin>Wiley Heyden Ltd., Chichester and Akadémiai Kiadó, Budapest, 1978</recordOrigin><recordIdentifier>10973_1978_Article_BF01912382.pdf</recordIdentifier></recordInfo></mods></record>Pour manipuler ce document sous Unix (Dilib)
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